First, we must understand that Paul is the perfect interpreter of Isaiah 54:1 which he quotes here. He does not bend it to suit his own purpose, but quotes it to show Old Testament support for his doctrine and therefore lets it speak for itself unchanged.
This passage in Isaiah is not about Sarah and Hagar as some think, who link it to Isaiah 51:2. Neither Sarah nor Hagar could be described as without a husband for both were the wives of Abraham, and their respective children do not fit Isaiah’s picture. In quoting Isaiah, Paul has introduced a new picture of the realities that Sarah and Hagar represent. What Isaiah 54:1 adds is the further glorious truth that Jerusalem above is to see wonderful blessing and expansion in the gathering in of the Gentiles. Of course not all Gentiles come to faith, but a vast number have been converted and these are the fulfilment of Isaiah’s prophecy. The comparison is not between believing Gentiles and believing Jews, but between the elect Gentiles and ethnic Jews, between those in the Old Covenant and those in the New.